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VOL. 1, ISSUE 1 (2025)
Electron paramagnetic resonance (EPR) spectroscopy
Authors
Maroj Bharati
Abstract
Electron Paramagnetic Resonance (EPR) Spectroscopy is a powerful and widely used analytical technique to investigate materials with unpaired electrons, such as transition metal ions, radicals, and defects in solids, liquids, and biological systems. EPR detects the interaction of unpaired electron spins with an external magnetic field, providing detailed information about the local environment, magnetic interactions, electronic structure, and spin dynamics of the species under study. The technique is particularly valuable for characterizing paramagnetic centers in complex materials, where it allows for the determination of g-factors, hyperfine interactions, and zero-field splitting (ZFS). EPR is employed in a variety of fields including materials science, chemistry, biophysics, and solid-state physics to probe radicals, transition metal complexes, defects in semiconductors, and biological systems. In this review, we explore the fundamental principles of EPR, the instrumentation involved, and its applications to study the electronic structure and magnetic properties of paramagnetic materials. We also discuss recent advancements in the technique, including pulse EPR and spin labeling, which offer higher resolution and greater sensitivity for complex systems.
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Pages:11-15
How to cite this article:
Maroj Bharati "Electron paramagnetic resonance (EPR) spectroscopy". World Journal of Physics and Applications, Vol 1, Issue 1, 2025, Pages 11-15
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